Supramolecular Complexes for Quantum Simulation

Supramolecular Complexes for Quantum Simulation

Simulating the evolution of quantum systems on a classical computer is a yellow very challenging task, which could be easily tackled by digital quantum simulators. These are intrinsically quantum devices whose parameters can be controlled in order to mimic the evolution of a broad class of target Hamiltonians. We describe here a quantum simulator implemented on a linear register of molecular Cr...

Helicates as Versatile Supramolecular Complexes.

Supramolecular Complexes and Supramolecular Catalysts Formed by Molecular Assembly of Multinuclear Metal Complexes in Aqueous Solutions

Quantum-Chemical Insights into the Self-Assembly of Carbon-Based Supramolecular Complexes.

Understanding how molecular systems self-assemble to form well-organized superstructures governed by noncovalent interactions is essential in the field of supramolecular chemistry. In the nanoscience context, the self-assembly of different carbon-based nanoforms (fullerenes, carbon nanotubes and graphene) with, in general, electron-donor molecular systems, has received increasing attention as a...

Photoresponsive Supramolecular Complexes as Efficient DNA Regulator

Two supramolecular complexes of trans-1⊂CB[8] and trans-2⊂CB[8] were successfully achieved by the controlled selective complexation process of cucurbit[8]uril (CB[8]) with hetero-guest pair containing azobenzene and bispyridinium moieties in aqueous solution, exhibiting the reversibly light-driven movements of CB[8] upon the photocontrollable isomerization of azophenyl axle components. Signific...